– Metal complexes in Radiodiagnosis. – Materials based on coordination polymers. – Coordination compounds in drug delivery.
2017
2018
2019
2020
Scientific Papers
Gómez-Paz O, Carballo R, Lago AB, Vázquez-López EM. Polymorphism in a two-dimensional copper(i) metal–organic framework with the ligand bis(4-pyridylthio)methane. CrysEngComm. 2021;23:4658-4666.https://doi.org/10.1039/D1CE00461A +DOI
Gómez-Paz O, Carballo R, Lago AB, Vázquez-López EM. Polymorphism in a two-dimensional copper(i) metal–organic framework with the ligand bis(4-pyridylthio)methane. CrystEngComm. 2021;23(26):4658–66. DOI: 10.1039/D1CE00461A. https://doi.org/10.1039/D1CE00461A%0A +DOI
Lago AB, Pino-Cuevas A, Carballo R, Vázquez-López EM. Effect of N -salicylidene hydrazide protonation on the solid state structural diversity of its Cu( ii ), Ni( ii ) and Zn( ii ) complexes. CrystEngComm. 2021;23(1):153–62. DOI: 10.1039/D0CE01204A. https://doi.org/10.1039/D0CE01204A%0A +DOI
Lago AB, Pino-Cuevas A, Carballo R, Vázquez-López EM. Effect of N-salicylidene hydrazide protonation on the solid state structural diversity of its Cu(ii), Ni(ii) and Zn(ii) complexes. CrystEngComm.;23:153-162. https://doi.org/10.1039/D0CE01204A +DOI
Rouco L, Sánchez-González Á, Alvariño R, Alfonso A, Vázquez-López EM, García-Martínez E, Maneiro M. Combined Effect of Caspase-Dependent and Caspase-Independent Apoptosis in the Anticancer Activity of Gold Complexes with Phosphine and Benzimidazole Derivatives. Pharmaceuticals (Basel). 2020 Dec 24;14(1). pii: 10. doi: 10.3390/ph14010010. PubMed PMID: 33374177; PubMed Central PMCID: PMC7824672. +Pubmed+DOI
Rouco L, Sánchez-González Á, Alvariño R, Alfonso A, Vázquez-López EM, García-Martínez E, Maneiro M. Combined Effect of Caspase-Dependent and Caspase-Independent Apoptosis in the Anticancer Activity of Gold Complexes with Phosphine and Benzimidazole Derivatives. Pharmaceuticals (Basel). 2021 Dec;14(1):10. PMID: 33374177. DOI: 10.3390/ph14010010. http://www.ncbi.nlm.nih.gov/pubmed/33374177 +Pubmed+DOI
Scientific Papers
Argibay-Otero S, Gano L, Fernandes C, Paulo A, Carballo R, Vázquez-López EM. Chemical and biological studies of Re(I)/Tc(I) thiosemicarbazonate complexes relevant for the design of radiopharmaceuticals. J Inorg Biochem. 2020;203:110917. PMID: 31766012. DOI: 10.1016/j.jinorgbio.2019.110917. http://www.ncbi.nlm.nih.gov/pubmed/31766012 +Pubmed+DOI
Argibay-Otero S, Graña AM, Carballo R, Vázquez-López EM. Synthesis of Novel Dinuclear N-Substituted 4-(Dimethylamino)benzaldehyde Thiosemicarbazonates of Rhenium(I): Formation of Four- and/or Five-Membered Chelate Rings, Conformational Analysis, and Reactivity. Inorg Chem. 2020 Oct;59(19):14101–17. PMID: 32965111. DOI: 10.1021/acs.inorgchem.0c01887. http://www.ncbi.nlm.nih.gov/pubmed/32965111 +Pubmed+DOI
García-Raso A, Terrón A, Ortega-Castro J, Barceló-Oliver M, Lorenzo J, Rodríguez-Calado S, Franconetti A, Frontera A, Vázquez-López EM, Fiol JJ. Iridium(III) coordination of N(6) modified adenine derivatives with aminoacid chains. J Inorg Biochem. 2020;205:111000. PMID: 31982811. DOI: 10.1016/j.jinorgbio.2020.111000. http://www.ncbi.nlm.nih.gov/pubmed/31982811 +Pubmed+DOI
Tavassoli M, Montazerozohori M, Naghiha R, Sadeghi H, Masoudiasl A, Joohari S, Lopez EV, Mahmoudi G. Some new nanostructure zinc complex: Synthesis, spectral analyses, crystal structure, Hirshfeld surface analyses, antimicrobial/anticancer, thermal behavior and usage as precursor for ZnO nanostructure. Mater Sci Eng C Mater Biol Appl. 2020 May;110:110642. PMID: 32204075. DOI: 10.1016/j.msec.2020.110642. http://www.ncbi.nlm.nih.gov/pubmed/32204075 +Pubmed+DOI
Scientific Papers
García-Raso A, Terrón A, López-Zafra A, García-Viada A, Barta A, Frontera A, Lorenzo J, Rodríguez-Calado S, Vázquez-López EM, Fiol JJ. Crystal structures of N 6 -modified-amino acid related nucleobase analogs (II): hybrid adenine-?-alanine and adenine-GABA molecules. New J Chem. 2019 Jun;43(24):9680–8. DOI: 10.1039/C9NJ02279A. http://doi.org/10.1039/C9NJ02279A +DOI
Pino-Cuevas A, Raposinho PD, Fernandes C, Paulo A, Abram U, Carballo R, Vázquez-López EM. Thiosemicarbazonate complexes with affinity for amyloid-? fibers: synthesis, characterization and biological studies. Future Med Chem. 2019 Oct;11(19):2527–46. PMID: 31633404. DOI: 10.4155/fmc-2019-0013. http://www.ncbi.nlm.nih.gov/pubmed/31633404 +Pubmed+DOI
Scientific Papers
Carballo R, Castiñeiras A, Covelo B, Lago AB, Vázquez-López EM, Gómez-Paz O, Balboa S, Prieto I. Chiral and achiral 1D copper (II) coordination polymers based on glycolato and chelating aromatic diamine ligands. CrystEngComm. 2018 May;20(17):2455–64. DOI: 10.1039/C8CE00279G. http://xlink.rsc.org/?DOI=C8CE00279G +DOI
Carballo R, Covelo B, Gómez-Paz O, Lago AB, Vázquez-López EM. Supramolecular metal–organic frameworks based on neutral and cationic copper(II) ?-hydroxycarboxylate complexes with 2,2?-dipyridylamine. Polyhedron. 2018 Nov;154:398–406. DOI: 10.1016/j.poly.2018.07.056. https://linkinghub.elsevier.com/retrieve/pii/S0277538718304558 +DOI
Casas JS, Couce MD, Sánchez A, Seoane R, Sordo J, Perez-Estévez A, Vázquez-López E. Triphenyltin derivatives of sulfanylcarboxylic esters. J Inorg Biochem. 2018 Mar;180:163–70. PMID: 29291491. DOI: 10.1016/j.jinorgbio.2017.12.009. http://www.ncbi.nlm.nih.gov/pubmed/29291491 +Pubmed+DOI
García-Raso A, Terrón A, Bauzá A, Frontera A, Molina JJ, Vázquez-López EM, Fiol JJ. Crystal structures of N 6 -modified-aminoacid/peptide nucleobase analogs: hybrid adenine–glycine and adenine–glycylglycine molecules. New J Chem. 2018;42(18):14742–50. DOI: 10.1039/C8NJ02147C. http://xlink.rsc.org/?DOI=C8NJ02147C +DOI
Pino-Cuevas A, Graña A, Abram U, Carballo R, Vázquez-López EM. Structural study of mono-, di- and tetranuclear complexes of the {Re(CO) 3 } + fragment with thiosemicarbazone/thiosemicarbazonate ligands containing benzothiazole or benzoxazole groups. CrystEngComm. 2018;20(33):4781–92. DOI: 10.1039/C8CE00874D. http://xlink.rsc.org/?DOI=C8CE00874D +DOI
Scientific Papers
Akçay HT, Çoruh U, Bayrak R, Mente?e E, Vazquez Lopez EM. A spectroscopic study on new phthalonitrile derivative and its computational background: 4-[(4,5-Diphenyl-4H-1,2,4-triazol-3-yl)sulfanyl]benzene-phthalonitrile. J Mol Struct. 2017 Jan;1127:539–48. DOI: 10.1016/j.molstruc.2016.08.016. IF2017: 2.011; Q3. http://linkinghub.elsevier.com/retrieve/pii/S0022286016308468 +DOI
Casas JS, Castiñeiras A, Couce MD, Sánchez A, Sordo J, Vázquez-López E. New Tin-Oxometallates from the Hydrolysis of SnEt 2 2+ in the Presence of 2,6-Lutidine-? 2 ,3-Diol and different Anions. ChemistrySelect. 2017 Feb;2(5):1983–91. DOI: 10.1002/slct.201601877. IF2017:1.505; Q3. http://doi.wiley.com/10.1002/slct.201601877 +DOI
Mahmoudi G, Gurbanov A V., Rodríguez-Hermida S, Carballo R, Amini M, Bacchi A, Mitoraj MP, Sagan F, Kuku?ka M, Safin DA. Ligand-Driven Coordination Sphere-Induced Engineering of Hybride Materials Constructed from PbCl2 and Bis-Pyridyl Organic Linkers for Single-Component Light-Emitting Phosphors. Inorg Chem. 2017 Aug;56(16):9698–709. PMID: 28753278. DOI: 10.1021/acs.inorgchem.7b01189. IF2017: 4.700; Q1. http://www.ncbi.nlm.nih.gov/pubmed/28753278 +Pubmed+DOI
Mahmoudi G, Zangrando E, Bauzá A, Maniukiewicz W, Carballo R, Gurbanov A V., Frontera A. Molecular and crystalline architectures based on HgI 2?: from metallamacrocycles to coordination polymers. CrystEngComm. 2017;19(24):3322–30. DOI: 10.1039/C7CE00628D. IF2017: 3.304; Q2. http://xlink.rsc.org/?DOI=C7CE00628D +DOI
Núñez-Montenegro A, Argibay-Otero S, Carballo R, Graña A, Vázquez-López EM. Supramolecular Synthesis and Experimental and Theoretical Studies of Cocrystal Systems Based on Resorcinol-Thiosemicarbazones and N,N?-Divergent Dipyridines. Cryst Growth Des. 2017 Jun;17(6):3338–49. DOI: 10.1021/acs.cgd.7b00304. IF2017: 3.972; Q1. http://pubs.acs.org/doi/10.1021/acs.cgd.7b00304 +DOI
Scientific Papers
Casas JS, Castaño MV, Couce MD, Sánchez A, Sordo J, Torres MD, Vázquez SA, Vázquez-López EM. Relevance of weak intermolecular forces on the supramolecular structure of free or DMSO solvated 5-(4-X-benzylidene)rhodanines (X = F, Cl, Br, I). J Mol Struct. 2016 Sep;1120:100–14. DOI: 10.1016/j.molstruc.2016.05.010. IF2016: 1.753; Q3. http://linkinghub.elsevier.com/retrieve/pii/S0022286016304458 +DOI
Casas JS, Couce MD, García-Vega M, Sánchez A, Sordo J, Vázquez López EM. Phenylmercury( ii ) sulfanylpropenoates: an example of symmetrization with the 3-(2-methoxyphenyl)-2-sulfanylpropenoato ligand. New J Chem. 2016 Aug;40(8):6735–44. DOI: 10.1039/C6NJ00624H. IF2016: 3.269; Q2. http://xlink.rsc.org/?DOI=C6NJ00624H +DOI
Lago AB, Pino-Cuevas A, Carballo R, Vázquez-López EM. A new metal-organic polymeric system capable of stimuli-responsive controlled release of the drug ibuprofen. Dalton Trans. Royal Society of Chemistry; 2016 Jan;45(4):1614–21. PMID: 26692254. DOI: 10.1039/c5dt04031k. IF2016: 4.029; Q1. http://www.ncbi.nlm.nih.gov/pubmed/26692254 +Pubmed+DOI
Rodríguez-Hermida S, Lago AB, Pino-Cuevas A, Hagenbach A, Cañadillas-Delgado L, Carballo R, Abram U, Vázquez-López EM. A Hexameric Cationic Copper(II) Metallacrown as a Pertechnetate and Perrhenate Scavenger. Chemistry. 2016 Jan;22(5):1847–53. PMID: 26671639. DOI: 10.1002/chem.201504315. IF2016: 5.317; Q1. http://www.ncbi.nlm.nih.gov/pubmed/26671639 +Pubmed+DOI
Scientific Papers
Carballo R, Covelo B, Lago AB, Pino-Cuevas A, Vázquez-López EM. Exploration of the solid state metallosupramolecular chemistry of mononuclear nickel(II) complexes with ?-hydroxycarboxylates and 2,2?-dipyridylamine. Polyhedron. 2015 Jan;85:124–30. DOI: 10.1016/j.poly.2014.08.037. IF2015: 2.108; Q2. http://linkinghub.elsevier.com/retrieve/pii/S0277538714005592 +DOI
Casas JS, Castaño MV, Couce MD, Sánchez A, Sordo J, Torres MD, Vázquez López EM. New diorganolead(IV) sulfanylpropenoates: Synthesis, characterization and analysis of their evolution in DMSO solution. J Organomet Chem. 2015 Aug;789–790:29–39. DOI: 10.1016/j.jorganchem.2015.04.036. IF2015: 2.336; Q2. http://www.sciencedirect.com/science/article/pii/S0022328X1500248X +DOI
Casas JS, Castiñeiras A, Condori F, Couce MD, Sánchez A, Sordo J, Vázquez-López E. Tin Oxometallates from the Hydrolysis of SnMe 2 2+ in the Presence of 2,6-Lutidine-? 2 ,3-diol and Different Anions. Eur J Inorg Chem. 2015 May;2015(14):2387–401. DOI: 10.1002/ejic.201500127. IF2015: 2.686; Q2. http://doi.wiley.com/10.1002/ejic.201500127 +DOI
Emirik M, Karao?lu K, Serbest K, Çoruh U, Vazquez Lopez EM. Two novel unsymmetrical ferrocene based azines and their complexing abilities towards Cu(II): Spectroscopy, crystal structure, electrochemistry and DFT calculations. Polyhedron. 2015 Feb;88:182–9. DOI: 10.1016/j.poly.2014.12.044. IF2015: 2.108; Q2. http://www.sciencedirect.com/science/article/pii/S0277538715000121 +DOI
Pino-Cuevas A, Carballo R, Muñoz L, Vázquez-López EM. Rhenium Complexes of Ligands Based on Stilbene – Synthesis, Characterization, Reactivity, and Conformational Analysis. Eur J Inorg Chem. 2015 Sep;2015(26):4402–11. DOI: 10.1002/ejic.201500500. IF2015: 2.686; Q2. http://doi.wiley.com/10.1002/ejic.201500500 +DOI
Ragon F, Campo B, Yang Q, Martineau C, Wiersum AD, Lago A, Guillerm V, Hemsley C, Eubank JF, Vishnuvarthan M, Taulelle F, Horcajada P, Vimont A, Llewellyn PL, Daturi M, Devautour-Vinot S, Maurin G, Serre C, Devic T, Clet G. Acid-functionalized UiO-66(Zr) MOFs and their evolution after intra-framework cross-linking: structural features and sorption properties. J Mater Chem A. The Royal Society of Chemistry; 2015 Feb;3(7):3294–309. DOI: 10.1039/C4TA03992K. IF2015: 8.262; D1. http://pubs.rsc.org/en/content/articlehtml/2015/ta/c4ta03992k +DOI
Rodríguez-Hermida S, Lago AB, Carballo R, Fabelo O, Vázquez-López EM. Homo- and heteronuclear compounds with a symmetrical bis-hydrazone ligand: synthesis, structural studies, and luminescent properties. Chemistry. 2015 Apr;21(17):6605–16. PMID: 25760669. DOI: 10.1002/chem.201405962. IF2015: 5.771; Q1. http://www.ncbi.nlm.nih.gov/pubmed/25760669 +Pubmed+DOI
Scientific Papers
Barreiro E, Casas JS, Couce MD, Sánchez A, Sánchez-Gonzalez A, Sordo J, Vázquez-López EM. Mono and dinuclear phosphinegold(I) sulfanylcarboxylates: influence of nuclearity and substitution of PPh3 for PEt3 on cytotoxicity. J Inorg Biochem. 2014 Sep;138:89–98. PMID: 24935091. DOI: 10.1016/j.jinorgbio.2014.05.010. IF: 3.444; Q1. http://www.ncbi.nlm.nih.gov/pubmed/24935091 +Pubmed+DOI
Barreiro E, Casas JS, Couce MD, Sánchez A, Sordo J, Vázquez-López EM. Heteronuclear gold(I)-silver(I) sulfanylcarboxylates: Synthesis, structure and cytotoxic activity against cancer cell lines. J Inorg Biochem. 2014 Feb;131:68–75. PMID: 24269769. DOI: 10.1016/j.jinorgbio.2013.10.022. IF: 3.444; Q1. http://www.ncbi.nlm.nih.gov/pubmed/24269769 +Pubmed+DOI
Carballo R, Pino-Cuevas A, Vázquez-López EM. Crystal structure of 1-(4-formyl-benzyl-idene)thio-semicarbazone. Acta Crystallogr Sect E Struct Rep Online. 2014 Sep;70(Pt 9):o970. PMID: 25309285. DOI: 10.1107/S1600536814017255. IF: 0.347; Q4. http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=4186181&tool=pmcentrez&rendertype=abstract +Pubmed+DOI
Núñez-Montenegro A, Carballo R, Vázquez-López EM. Synthesis, characterization and binding affinities of rhenium(I) thiosemicarbazone complexes for the estrogen receptor (?/?). J Inorg Biochem. 2014 Nov;140:53–63. PMID: 25061691. DOI: 10.1016/j.jinorgbio.2014.06.012. IF: 3.444; Q1. http://www.ncbi.nlm.nih.gov/pubmed/25061691 +Pubmed+DOI
Núñez-Montenegro A, Pino-Cuevas A, Carballo R, Vázquez-López EM. Structural evidence of an intramolecular proton transfer leading to keto-amine tautomer in the crystals of Schiff bases derived from tyrosine and histidine esters. J Mol Struct. 2014 Mar;1062:110–5. DOI: 10.1016/j.molstruc.2014.01.023. IF: 1.634; Q3. http://linkinghub.elsevier.com/retrieve/pii/S002228601400057X +DOI
Pino-Cuevas A, Carballo R, Vázquez-López EM. Crystal structure of 1-(4-formyl-benzyl-idene)-4-methyl-thio-semicarbazone. Acta Crystallogr Sect E Struct Rep Online. 2014 Sep;70(Pt 9):o926. PMID: 25309257. DOI: 10.1107/S1600536814016407. IF: 0.347; Q4. http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=4186068&tool=pmcentrez&rendertype=abstract +Pubmed+DOI
Code
PID2019-110218RB-I00
Title
Estrategias basadas en complejos para el diagnóstico y tratamiento del cancer de pulmón de célula no pequeña
Funder
Ministerio de Ciencia e Innovación
Type
Individual
Duration
2020 – 2023
PI
Ezequiel M. Vázquez López
Cols.
I. Prieto. M. Couce. M. García. O. Gómez. R. Carballo. S. Argibay
Code
IN606A-2019/025
Title
Axuda de apoio á etapa predoutoral 2019 – Modalidade B
Funder
Axencia Galega de Innovación
Type
Individual
Duration
2019 – 2022
PI
Olaya Gómez Paz
Cols.
E. Vázquez
Code
CTQ2017-90802-REDT
Title
Red de Iones Metálicos en Sistemas Biológicos (MetalBio17)
Funder
Ministerio de Economía y Competitividad
Type
Multicéntrico
Duration
2018 – 2020
PI
Ezequiel M. Vázquez López
Cols.
I. Prieto. M. Couce. R. Carballo. S. Argibay
Code
ED431D 2017/01
Title
Rede Galega de Investigación de Metais en Sistemas Biolóxicos
Funder
Consellería de Cultura, Educación e Ordenación Universitaria
Type
Multicéntrico
Duration
2017 – 2020
PI
Marcelino Maneiro (External PI)
Coordinator
Marcelino Maneiro (Coord. Universidad de Santiago de Compostela)
Cols.
E. Vázquez. I. Prieto. M. Couce. R. Carballo. S. Argibay
Code
CTQ2015-70901-R
Title
Radiofármacos basados en complejos metálicos para la obtención de imágenes del receptor de estrógeno y acumulaciones de betaamiloide
Funder
Ministerio de Economía y Competitividad
Type
Individual
Duration
2016 – 2018
PI
Ezequiel M. Vázquez López
Cols.
I. Prieto. R. Carballo
Code
CTQ2015-71211-REDT
Title
Red de iones metálicos en sistemas biológicos
Funder
Ministerio de Economía y Competitividad
Type
Coordinado
Duration
2015 – 2017
PI
Ezequiel M. Vázquez López
Code
2014/004
Title
Rede galega de investigación de ións metálicos en sistemas biolóxicos
Funder
Consellería de Cultura, Educación e Ordenación Universitaria
Type
Multicéntrico
Duration
2014 – 2015
PI
Manuel Rafael Bermejo Patiño (External PI)
Cols.
E. Vázquez. I. Prieto. R. Carballo
Code
CTQ2010-19386/BQU
Title
Complexos Metálicos en Radiodiagnosis, COMERA
Funder
Ministerio de Educación, Cultura y Deporte
Type
Individual
Duration
2010 – 2014
PI
Ezequiel M. Vázquez López
Cols.
I. Prieto. R. Carballo
Title
Estudio de la reactividad de complejos semi-sandwich de rutenio(II) e iridio(III)
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